Transformation of cyclohexene to enantiopure cyclitols mediated by sequential oxyselenenylation with (S,S)-hydrobenzoin:: synthesis of D-chiro-inositol and muco-quercitol

被引：38

作者：

Kim, KS ^{[1
]}

Park, JI ^{[1
]}

Moon, HK ^{[1
]}

Yi, H ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 18期

关键词：

D O I：

10.1039/a804072i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxyselenenylation of cyclohexene with (S,S)-hydrobenzoin and subsequent oxidation-elimination allows isolation of an allylic ether in which further phenylselenenylation is completely regioselective, thus allowing entry to the cyclitols D-chiro-inositol and muco-quercitol.

引用

页码：1945 / 1946

页数：2

共 15 条

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