Stereoselective methoxyselenenylation of acyclic allylic alcohol derivatives: A method for the synthesis of 1,3-anti-diols

被引：15

作者：

Kim, KS ^{[1
]}

Park, HB ^{[1
]}

Kim, JY ^{[1
]}

Ahn, YH ^{[1
]}

Jeong, IH ^{[1
]}

机构：

[1] YONSEI UNIV,DEPT CHEM,WONJU 220710,SOUTH KOREA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 08期

关键词：

D O I：

10.1016/0040-4039(95)02408-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of secondary acyclic trans-allylic alcohol derivatives with PhSeBr in the presence of 2,6-di-t-butylpyridine in MeOH proceeded in a highly regio- and stereoselective manner and the subsequent reduction and deprotection of the resultant methoxyselenides afforded mostly 1,3-anti-diols. The methoxyselenenylation of the acetate derivative of the same allylic alcohol, on the other hand, gave several other isomers along with the 1,3-anti-diol derivative.

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收藏

页码：1249 / 1252

页数：4

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