Regioselective reductive demethoxylation of 3,4,5-trimethoxystilbenes

被引：31

作者：

Azzena, U ^{[1
]}

Dettori, G ^{[1
]}

Idini, MV ^{[1
]}

Pisano, L ^{[1
]}

Sechi, G ^{[1
]}

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

TETRAHEDRON | 2003年 / 59卷 / 40期

关键词：

reduction; electron transfer; regioselectivity; stilbenes;

D O I：

10.1016/j.tet.2003.08.009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selective removal of the 4-methoxy group of 3,4,5-trimethoxystilbenes was performed under electron transfer conditions from Na metal in THF. Careful control of reaction conditions and quenching procedure allowed the synthesis of either (E)-3,5-dimethoxystilbenes or 3,5-dimethoxybibenzyls. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：7961 / 7966

页数：6

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