1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: A new and powerful nonderivatizing solvent for cellulose

被引：1289

作者：

Zhang, H ^{[1
]}

Wu, J ^{[1
]}

Zhang, J ^{[1
]}

He, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China

来源：

MACROMOLECULES | 2005年 / 38卷 / 20期

关键词：

D O I：

10.1021/ma0505676

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new and highly efficient direct solvent, 1-allyl-3-methylimidazolium chloride (AMIMCI), has been used for the dissolution and regeneration of cellulose. The cellulose samples without any pretreatment were readily dissolved in AMIMCI. The regenerated cellulose materials prepared by coagulation in water exhibited a good mechanical property. Because of its thermostable and nonvolatile nature, AMIMCI was easily recycled. Therefore, a novel and nonpolluting process for the manufacture of regenerated cellulose materials using AMIMCI has been developed in this work.

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页码：8272 / 8277

页数：6

相关论文

共 45 条

[1] Characterizing ionic liquids on the basis of multiple solvation interactions [J].

Anderson, JL ;

Ding, J ;

Welton, T ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14247-14254

[2] THE LITHIUM CHLORIDE/DIMETHYLACETAMIDE SOLVENT FOR CELLULOSE - A LITERATURE-REVIEW [J].

DAWSEY, TR ;

MCCORMICK, CL .

JOURNAL OF MACROMOLECULAR SCIENCE-REVIEWS IN MACROMOLECULAR CHEMISTRY AND PHYSICS, 1990, C30 (3-4) :405-440

[3] SYNTHESIS AND PROPERTIES OF CELLULOSE ACETOACETATES [J].

EDGAR, KJ ;

ARNOLD, KM ;

BLOUNT, WW ;

LAWNICZAK, JE ;

LOWMAN, DW .

MACROMOLECULES, 1995, 28 (12) :4122-4128

[4] Structure formation of regenerated cellulose materials from NMMO-solutions [J].

Fink, HP ;

Weigel, P ;

Purz, HJ ;

Ganster, J .

PROGRESS IN POLYMER SCIENCE, 2001, 26 (09) :1473-1524

[5] The behaviour of cellulose in hydrated melts of the composition LiX•nH2O (X = I-, NO3-, CH3COO-, ClO4-) [J].

Fischer, S ;

Voigt, W ;

Fischer, K .

CELLULOSE, 1999, 6 (03) :213-219

[6] Controlling the aqueous miscibility of ionic liquids: Aqueous biphasic systems of water-miscible ionic liquids and water-structuring salts for recycle, metathesis, and separations [J].

Gutowski, KE ;

Broker, GA ;

Willauer, HD ;

Huddleston, JG ;

Swatloski, RP ;

Holbrey, JD ;

Rogers, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (22) :6632-6633

[7] New solvents for cellulose: Hydrazine/thiocyanate salt system [J].

Hattori, K ;

Cuculo, JA ;

Hudson, SM .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (04) :601-611

[8]

Heinze T, 2000, MACROMOL CHEM PHYSIC, V201, P627, DOI 10.1002/(SICI)1521-3935(20000301)201:6<627::AID-MACP627>3.3.CO

[9]

2-P

[10] Unconventional methods in cellulose functionalization [J].

Heinze, T ;

Liebert, T .

PROGRESS IN POLYMER SCIENCE, 2001, 26 (09) :1689-1762

← 1 2 3 4 5 →