New Catalysts for the Transition-Metal-Catalyzed Synthesis of Aziridines

被引：67

作者：

Jung, Nicole ^{[2
]}

Braese, Stefan ^{[1
]}

机构：

[1] Inst Organ Chem, D-76131 Karlsruhe, Germany

[2] Inst Toxikol & Genet ITG, D-76344 Eggenstein Leopoldshafen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 23期

关键词：

azides; aziridine synthesis; homogeneous catalysis; porphyrinoids; transition metals; ARYL AZIDES; ALKENES; OLEFINS; PORPHYRIN;

D O I：

10.1002/anie.201200966

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C 2+N 1: The transition-metal-catalyzed reaction of alkenes with azides is an important tool for the formation of aziridines. Besides many recently published ruthenium, copper, and manganese catalysts, a novel macrocyclic tetracarbene iron(II) catalyst promotes the synthesis of aziridines in good yields and with low catalyst loadings. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5538 / 5540

页数：3

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