Catalytic amination of unsaturated hydrocarbons:: reactions of p-nitrophenylazide with alkenes catalysed by metallo-porphyrins

被引：70

作者：

Cenini, S ^{[1
]}

Tollari, S ^{[1
]}

Penoni, A ^{[1
]}

Cereda, C ^{[1
]}

机构：

[1] Ctr CNR, I-20133 Milan, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 137卷 / 1-3期

关键词：

alkenes; amination; organic azides; metallo-porphyrins;

D O I：

10.1016/S1381-1169(98)00116-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Porphyrin derivatives of transition metals such as Ru(TPP)CO, Ru(OEP)CO and Co(OEP)(TPP = dianion of 5, 10, 15, 20-tetraphenylporphyrin, OEP=dianion of 2, 3, 7, 8, 12, 13, 17, 18-octaetylporphyrin) catalyse the reaction of p-nitrophenylazide with cyclohexene to give the corresponding allylamine in good yields. With other olefins such as cyclooctene, 1-octene, styrene and substituted styrenes the main product becomes the corresponding aziridine. The reaction of p-nitrophenylazide with Ru(TPP)CO has been investigated and the mechanism of the catalytic reactions is discussed. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：135 / 146

页数：12

共 23 条

[1] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].