High pressure synthesis of Mg0.90Al0.08Ni0.94V0.08H1.6

被引：5

作者：

Chen, J ^{[1
]}

Sakai, T ^{[1
]}

Kitamura, N ^{[1
]}

Takeshita, HT ^{[1
]}

Kuriyama, N ^{[1
]}

机构：

[1] Osaka Natl Res Inst, AIST, MITI, Ikeda, Osaka 5638577, Japan

来源：

METALS AND MATERIALS-KOREA | 2000年 / 6卷 / 06期

关键词：

high pressure; heating; Mg-based alloy; X-ray diffraction; thermal analysis;

D O I：

10.1007/BF03028107

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The effect of high-pressure (6 gigapascal) and heating (600 degreesC) the hydrogen source of LiAlH4 on the structural and hydrogenation properties of 0.9MgH(2)+0.1Al+0.9Ni+0.1VH(0.9) was investigated. After recovery to ambient conditions, the sample was analyzed using X-ray diffraction, differential scanning calorimetry, thermogravimetry and differential thermal analyses. The results reveal that a nominal hydride phase with the composition of Mg0.90Al0.08Ni0.94V0.08H1.6 can be obtained, in which a maximum H-2-uptake can reach 1.9 wt.%, with hydride decomposition occurring between 160 degreesC and 250 degreesC.

引用

页码：605 / 608

页数：4

共 9 条

[1] A high pressure observation of the Mg2NiH4-H system [J].

Chen, J ;

Sakai, T ;

Kitamura, N ;

Tanaka, H ;

Takeshita, HT ;

Kuriyama, N ;

Harimoto, D ;

Nagai, H ;

Fukai, Y .

JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 307 :L1-L5

[2] FORMATION OF SUPERABUNDANT VACANCIES IN PD HYDRIDE UNDER HIGH HYDROGEN PRESSURES [J].

FUKAI, Y ;

OKUMA, N .

PHYSICAL REVIEW LETTERS, 1994, 73 (12) :1640-1643

[3] PRESSURE-INDUCED EFFECTS AND PHASE-RELATIONS IN MG2NIH4 [J].

GAVRA, Z ;

KIMMEL, G ;

GEFEN, Y ;

MINTZ, MH .

JOURNAL OF APPLIED PHYSICS, 1985, 57 (10) :4548-4551

[4]

NAYEBHASHEMI AA, 1986, BINARY ALLOY PHASE D, P1525

[5] Structural and hydriding properties of (Mg1-xAlx)Ni-H(D) with amorphous or CsCl-type cubic structure (x = 0-0.5) [J].

Orimo, S ;

Ikeda, K ;

Fujii, H ;

Saruki, S ;

Fukunaga, T ;

Zuttel, A ;

Schlapbach, L .

ACTA MATERIALIA, 1998, 46 (13) :4519-4525

[6] Structural and hydriding properties of the Mg-Ni-H system with nano- and/or amorphous structures [J].

Orimo, S ;

Ikeda, K ;

Fujii, H ;

Fujikawa, Y ;

Kitano, Y ;

Yamamoto, K .

ACTA MATERIALIA, 1997, 45 (06) :2271-2278

[7] Hydrogenation properties of Mg-based Laves phase alloys [J].

Tsushio, Y ;

Akiba, E .

JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 269 (1-2) :219-223

[8] Hydrogenation properties of MgNi0.86M10.03 (M1 = Cr, Fe, Co, Mn) alloys [J].

Tsushio, Y ;

Enoki, H ;

Akiba, E .

JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 281 (02) :301-305

[9] CATALYTIC EFFECT OF PD ON HYDROGEN ABSORPTION IN MECHANICALLY ALLOYED MG2NI, LANI5 AND FETI [J].

ZALUSKI, L ;

ZALUSKA, A ;

TESSIER, P ;

STROMOLSEN, JO ;

SCHULZ, R .

JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 217 (02) :295-300

← 1 →