Facilitated photoreduction of ruthenium bis(4'-methylterpyridine) pendant myoglobin

被引：14

作者：

Hamachi, I

Matsugi, T

Tanaka, S

Shinkai, S

机构：

[1] Dept. of Chem. Sci. and Technology, Faculty of Engineering, Kyushu University

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1996年 / 69卷 / 06期

关键词：

D O I：

10.1246/bcsj.69.1657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synthetic heme bearing ruthenium bis(terpyridine) through a covalent bond was successfully prepared. Ruthenium bis(terpyridine) pendant myoglobin, which was synthesized by a conventional cofactor reconstitution method, was efficiently activated through a photoinduced electron-transfer reaction from the ruthenium complex to the heme center. No reaction occurred in the corresponding intermolecular reaction system.

引用

页码：1657 / 1661

页数：5

共 16 条

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