Large Anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex

被引:47
作者
Ye, Qiong
Zhao, Hong
Qu, Zhi-Rong
Fu, Da-Wei
Xiong, Ren-Gen [1 ]
Cui, Yi-Ping
Akutagawa, Tomoyuki
Chan, Philip Wai Hong
Nakamura, Takayoshi
机构
[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China
[2] Southeast Univ, Sch Elect Sci & Engn, Nanjing 211189, Peoples R China
[3] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan
[4] Nanyang Technol Univ, Sch Math & Phys Sci, Div Chem & Biol Chem, Singapore 637616, Singapore
关键词
copper; deuterium; dielectric constant isotopic; effects; X-ray diffraction;
D O I
10.1002/anie.200700629
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Different directions: Huge and permanent anisotropy (see picture, left) was observed in an olefin copper complex (see structural formula, right). This phenomenon is likely due to weak D⋯Br interactions in the crystal. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6852 / 6856
页数:5
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