Reptation of star polymers in a network: Monte Carlo results of diffusion coefficients

被引:8
作者
Barkema, GT
Baumgaertner, A
机构
[1] Forschungszentrum Julich, Forum Modelierung, D-52425 Julich, Germany
[2] Univ Utrecht, NL-3584 CC Utrecht, Netherlands
关键词
D O I
10.1021/ma981330v
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We report on Monte Carlo results of diffusion coefficients of lattice star polymers trapped inside a fixed network (de Gennes model). It is found that our data are in agreement with the Helfand-Pearson exponential factor alpha = 0.29. For the preexponential power law exponent we find beta = 2. In contrast to existing theoretical predictions, we find that the number of arms f leads to a preexponential factor of the form exp(-0.75f).
引用
收藏
页码:911 / 914
页数:4
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