Three-dimensional crystal alignment using a time-dependent elliptic magnetic field

被引:66
作者
Kimura, T
Yoshino, M
机构
[1] Tokyo Metropolitan Univ, Dept Appl Chem, Tokyo 1920397, Japan
[2] Natl Inst Mat Sci, Tsukuba Magnet Lab, Tsukuba, Ibaraki 3050003, Japan
关键词
D O I
10.1021/la050182g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A theoretical study has been presented to show that it is possible to align. three different diamagnetic susceptibility axes (chi(3) < chi(2) < chi(1) < 0) of a crystallite with respect to the laboratory coordinate system (x, y, z). The time-dependent magnetic field that periodically changes in direction and intensity on the xy plane in an elliptic manner (the intensity stronger in the x direction) at a rate quicker than the intrinsic rate of magnetic response causes the three-dimensional alignment, that is, chi(1) parallel to x,chi(2) parallel to y, and chi(3) parallel to z. The fluctuation of the three susceptibility axes around the corresponding laboratory coordinates is estimated in terms of the fluctuation around the minimum of the time-averaged magnetic potential. This technique enables the three-dimensional alignment of the crystallographic axes.
引用
收藏
页码:4805 / 4808
页数:4
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