Reactions of lithium silenolates with benzophenone

被引：13

作者：

Ohshita, J

Sakurai, H

Masaoka, S

Tamai, M

Kunai, A

Ishikawa, M

机构：

[1] Hiroshima Univ, Dept Appl Chem, Grad Sch Engn, Higashihiroshima 7398527, Japan

[2] Kurashiko Univ Sci & Arts, Dept Chem Technol, Kurashiki, Okayama 7128505, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 633卷 / 1-2期

关键词：

enolate; silyllithium; carbonyl compounds;

D O I：

10.1016/S0022-328X(01)01071-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of lithium silenolates (Me3Si)(2)LiSiCOR (R = OCy, OAd, Mes) with benzophenone afforded 1,3-dioxa-2-silacyclopentanes as the major products. The crystal structure of a 1,3-dioxa-2-silacyclopentane was determined by an X-ray diffraction study. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：131 / 136

页数：6

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