Orthopalladated triarylphosphite complexes as highly efficient catalysts in the Heck reaction

被引：126

作者：

Albisson, DA ^{[1
]}

Bedford, RB ^{[1
]}

Scully, PN ^{[1
]}

机构：

[1] Trinity Coll, Dept Chem, Dublin 2, Ireland

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 52期

关键词：

Heck reactions; metalation; palladium and compounds; catalysis;

D O I：

10.1016/S0040-4039(98)02175-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An orthopalladated complex of commercially available tris(2,4-di-tert-butylphenyl)phosphite proves to be an extremely active catalyst in the Heck arylation of alkenes, with turnover numbers of up to 5,750,000 (mol product.mol Pd-1) and turnover frequencies of up to nearly 300,000 (mol product.mol Pd-1.h(-1)). (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9793 / 9796

页数：4

共 9 条

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