Asymmetric synthesis of alkaloid (-)-(2S,4S) SS 20846 A and its C-4 epimer

被引：17

作者：

Ripoche, I

Canet, JL

Aboab, B

Gelas, J

Troin, Y

机构：

[1] Univ Blaise Pascal, Ecole Natl Super Chim Clermont Ferrand, Lab Chim Heterocycles & Glucides, Ensemble Sci Cezeaux, F-63174 Aubiere, France

[2] SEESIB, Chim Organ Struct Lab, UMR 6504, F-63177 Aubiere, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 20期

关键词：

D O I：

10.1039/a804288h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A diastereoselective intramolecular Mannich reaction using;planar chiral iron dienal complexes is employed to prepare optically pure 2,4-disubstituted piperidines. This methodology is applied to the synthesis of natural alkaloids (-)-6 and (-)-7.

引用

页码：3485 / 3492

页数：8

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