ENANTIOPURE 2,3-DIHYDRO-4-PYRIDONES AS SYNTHETIC INTERMEDIATES - ASYMMETRIC SYNTHESES OF THE QUINOLIZIDINE ALKALOIDS (+)-MYRTINE, (-)-LASUBINE-I, AND (+)-SUBCOSINE-I

被引：77

作者：

COMINS, DL

LAMUNYON, DH

机构：

[1] Department of Chemistry, North Carolina State University, Raleigh

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 22期

关键词：

D O I：

10.1021/jo00048a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first asymmetric syntheses of three quinolizidine alkaloids, (+)-myrtine, (-)-lasubine I, and (+)-subcosine I, were accomplished with a high degree of stereocontrol from readily available 4-methoxy-3-(triisopropylsilyl)pyridine in three, four, and five steps, respectively.

引用

页码：5807 / 5809

页数：3

共 14 条

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