CO oxidation on rutile-supported Au nanoparticles

被引：357

作者：

Remediakis, IN ^{[1
]}

Lopez, N

Norskov, JK

机构：

[1] Tech Univ Denmark, Dept Phys, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark

[2] Univ Barcelona, Dept Quim Fis, E-08028 Barcelona, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 12期

关键词：

density functional calculations; gold; heterogeneous catalysis; nanostructures; titanium oxide;

D O I：

10.1002/anie.200461699

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

What makes inert gold active? The answer lies in controlling the structure of Au particles at the nanoscale: Either many interface sites or many low-coordinate Au atoms need to be present in the particles. This principle is demonstrated by modeling the oxidation of CO on a rutile (TiO 2)-supported Au nanocluster, the transition state of which does not involve the titania support (see picture: Au yellow, Ti light gray, C dark gray, O red). (Figure Presented) © 2005 Wiley-VCH Verlag GmbH S. Co. KGaA.

引用

页码：1824 / 1826

页数：3

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