A chloride resistant high potential oxygen reducing biocathode based on a fungal laccase incorporated into an optimized Os-complex modified redox hydrogel

被引：28

作者：

Beyl, Yvonne ^{[1
]}

Guschin, Dmitrii A. ^{[1
]}

Shleev, Sergey ^{[2
]}

Schuhmann, Wolfgang ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44780 Bochum, Germany

[2] Malmo Univ, Fac Hlth & Soc, Biomed Lab Sci, SE-20506 Malmo, Sweden

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2011年 / 13卷 / 05期

基金：

瑞典研究理事会;

关键词：

Laccase; Oxygen reduction; Chloride resistance; Redox polymer; Os-complex; Biofuel cell cathode; BIOFUEL CELLS; BILIRUBIN OXIDASE; ELECTRON-TRANSFER; MULTICOPPER OXIDASES; O-2; INHIBITION; REDUCTION; CATHODE; STABILITY; MECHANISM;

D O I：

10.1016/j.elecom.2011.02.024

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A chloride-resistant high-potential biocathode based on Trametes hirsuta laccase incorporated into an optimized Os-complex modified redox hydrogel (80 mV potential difference to the T1 Cu) is described. The bioelectrocatalytic activity towards O(2) reduction is due to an intimate access of the polymer-bound Os-complex to the T1 Cu site. The chloride resistance of the biocathode is due to the tight binding of the polymer-bound Os-complex to the T1 Cu site. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：474 / 476

页数：3

共 24 条

[1] Design of a bioelectrocatalytic electrode interface for oxygen reduction in biofuel cells based on a specifically adapted Os-complex containing redox polymer with entrapped Trametes hirsuta laccase [J].