Electron transfer in a hydrogen-bonded assembly consisting of porphyrin-diimide

被引：62

作者：

Osuka, A ^{[1
]}

Yoneshima, R

Shiratori, H

Okada, T

Taniguchi, S

Mataga, N

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

[2] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

[3] Osaka Univ, Res Ctr Mat Sci Extreme Condit, Toyonaka, Osaka 5608531, Japan

[4] Inst Laser Technol, Nishi Ku, Osaka 5500004, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a803541e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron-transfer reactions in an H-bonded assembly composed of a diacylaminopyridine bearing zinc porphyrin and 1,8: 4,5-naphthalenetetracarboxylic diimide (K-a = 2.8 x 10(2) dm(3) mol(-1)) in benzene occur with k(CS) = 4.1 x 10(10) s(-1) and k(CR) = 3.7 x 10(9) s(-1), while the corresponding covalently linked model with a comparable distance and energy gap undergoes electron transfer with k(CS) = 9.9 x 10(10) s(-1) and k(CR) = 6.7 X 10(8) s(-1).

引用

页码：1567 / 1568

页数：2

共 14 条

[1] MOLECULAR RECOGNITION .16. MOLECULAR RECOGNITION OF QUINONES - 2-POINT HYDROGEN-BONDING STRATEGY FOR THE CONSTRUCTION OF FACE-TO-FACE PORPHYRIN QUINONE ARCHITECTURES [J].

AOYAMA, Y ;

ASAKAWA, M ;

MATSUI, Y ;

OGOSHI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) :6233-6240

[2] The amidinium-carboxylate salt bridge as a proton-coupled interface to electron transfer pathways [J].

Deng, YQ ;

Roberts, JA ;

Peng, SM ;

Chang, CK ;

Nocera, DG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19) :2124-2127

[3] DIRECT EVALUATION OF ELECTRONIC COUPLING MEDIATED BY HYDROGEN-BONDS - IMPLICATIONS FOR BIOLOGICAL ELECTRON-TRANSFER [J].

DEREGE, PJF ;

WILLIAMS, SA ;

THERIEN, MJ .

SCIENCE, 1995, 269 (5229) :1409-1413

[4]

HAMILTON AD, 1988, PURE APPL CHEM, V60, P535

[5] MOLECULAR RECOGNITION VIA BASE-PAIRING - PHOTOINDUCED ELECTRON-TRANSFER IN HYDROGEN-BONDED ZINC PORPHYRIN BENZOQUINONE CONJUGATES [J].

HARRIMAN, A ;

KUBO, Y ;

SESSLER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (01) :388-390

[6] Photoinduced electron transfer between multifunctional porphyrin and ubiquinone analogues linked by several hydrogen-bonding interactions [J].

Hayashi, T ;

Miyahara, T ;

Kumazaki, S ;

Ogoshi, H ;

Yoshihara, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (17) :1964-1966

[7] FORMATION OF PORPHYRIN DONOR-ACCEPTOR COMPLEXES VIA AN AMIDINIUM-CARBOXYLATE SALT BRIDGE [J].

KIRBY, JP ;

VANDANTZIG, NA ;

CHANG, CK ;

NOCERA, DG .

TETRAHEDRON LETTERS, 1995, 36 (20) :3477-3480

[8] Significant effect of salt bridges on electron transfer [J].

Kirby, JP ;

Roberts, JA ;

Nocera, DG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (39) :9230-9236

[9] DESIGN AND SYNTHESIS OF COMPLEMENTARY COMPONENTS FOR THE FORMATION OF SELF-ASSEMBLED SUPRAMOLECULAR RIGID RODS [J].

KOTERA, M ;

LEHN, JM ;

VIGNERON, JP .

TETRAHEDRON, 1995, 51 (07) :1953-1972

[10] FEMTOSECOND PICOSECOND LASER PHOTOLYSIS STUDIES ON THE MECHANISMS OF ELECTRON-TRANSFER-INDUCED BY HYDROGEN-BONDING INTERACTIONS IN NONPOLAR SOLUTIONS - 1-AMINOPYRENE PYRIDINE SYSTEMS [J].

MIYASAKA, H ;

TABATA, A ;

KAMADA, K ;

MATAGA, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (16) :7335-7342

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