FORMATION OF PORPHYRIN DONOR-ACCEPTOR COMPLEXES VIA AN AMIDINIUM-CARBOXYLATE SALT BRIDGE

被引：66

作者：

KIRBY, JP ^{[1
]}

VANDANTZIG, NA ^{[1
]}

CHANG, CK ^{[1
]}

NOCERA, DG ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 20期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(95)00569-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Porphyrins have been modified with an amidine functional group and they have been shown to bind carboxylic acids to form a amidinium-carboxylate salt bridge. These systems offer a new model to probe the mechanism of proton-coupled electron transfer (PCET).

引用

页码：3477 / 3480

页数：4

共 26 条

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