X-ray structure and variable temperature NMR spectra of [meso-triarylcorrolato]copper(III)

被引：96

作者：

Brückner, C

Briñas, RP

Bauer, JAK

机构：

[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA

[2] Univ Cincinnati, Chem Dept Xray Facil, Cincinnati, OH 45221 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 15期

关键词：

D O I：

10.1021/ic034080u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diamagnetic square planar d(8) complexes [meso-arylcorrolato]copper(Ill) become paramagnetic upon warming, indicative of the equilibrium between the [corrolato]copper(III) and the [corrolato](+.) copper(II) forms of the complex. [meso-Triphenylcorrolato]copper(111) was structurally characterized and found to be saddled.

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页码：4495 / 4497

页数：3

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