Chiral polyoxometalate-induced enantiomerically 3D architectures: A new route for synthesis of high-dimensional chiral compounds

被引:182
作者
Tan, Huaqiao [1 ]
Li, Yangguang [1 ]
Zhang, Zhiming [1 ]
Qin, Chao [1 ]
Wang, Xinlong [1 ]
Wang, Enbo [1 ]
Su, Zhongmin [1 ]
机构
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
关键词
D O I
10.1021/ja073153w
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new enantiomerically chiral 3D architectures, L-(Zn(H2O)(3))(3)[MnMo9O32]center dot 4H(2)O and D-(Zn(H2O)(3))(3)[MnMo9O32]center dot 4H(2)O, have been produced from a new way. The compounds were composed of the discrete chiral [MnMo9O32](6-) polyoxoanions linked by zinc(II) atoms to a 3D framework with a 2-fold interpenetrating net, which is the first examples of POM-based chiral 3D frameworks consisting of only inorganic components.
引用
收藏
页码:10066 / 10067
页数:2
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