Performance enhancement of CdS-sensitized TiO2 mesoporous electrode with two different sizes of CdS nanoparticles

被引:39
作者
Chen, Haining [1 ]
Li, Weiping [1 ]
Liu, Huicong [1 ]
Zhu, Liqun [1 ]
机构
[1] Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China
关键词
Electrode architecture; Co-sensitization; Absorption spectrum; SOLAR-CELLS; QUANTUM DOTS; CO-SENSITIZATION;
D O I
10.1016/j.micromeso.2010.09.021
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In order to absorb broad spectrum and enhance the absorption in visible region, a novel electrode architecture is designed to co-sensitize TiO2 mesoporous film with two different sizes of CdS nanoparticles. Firstly, an added layer of CdS film with large size CdS nanoparticles (L-CdS) is coated on the TiO2 mesoporous film using spin-coating technique. Then the small size CdS nanoparticles (S-CdS) are deposited on TiO2/L-CdS mesoporous film by sequential chemical bath deposition method. The co-sensitization electrode (TiO2/L-CdS/S-CdS electrode) shows enhancement and broadening of absorption spectrum, in comparison with single-sensitization electrodes (TiO2/L-CdS and TiO2/S-CdS electrodes). The conversion efficiency of the semiconductor-sensitized solar cells (SSSCs) prepared with TiO2/L-CdS/S-CdS electrode is 1.60% which is higher than that of the SSSCs prepared with TiO2/L-CdS and TiO2/S-CdS electrodes. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码:235 / 238
页数:4
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