Polyions act as an electrostatic glue for mesoscopic particle aggregates

被引:24
作者
Bordi, F
Cametti, C
Sennato, S
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
[2] INFM, CRS, SOFT, Unita Roma 1, Rome, Italy
关键词
D O I
10.1016/j.cplett.2005.04.107
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Although complexation of charged particles induced by polyions of opposite charge is a well-known phenomenon, the possibility of obtaining equilibrium clusters stuck together by flexible polyions, which act as an electrostatic glue, is not completely recognized. In this Letter, we call attention towards the behavior of polyions in attaching together charged particles, by means of controlled electrostatic interactions. As an example, we present some features of equilibrium clusters composed of cationic liposomes built up by DOTAP and glued up by an anionic polyion, polyacrylate sodium salt. We discuss briefly some applications in nanostructure science and biotechnology. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:134 / 138
页数:5
相关论文
共 31 条
[1]   Effective charge versus bare charge: an analytical estimate for colloids in the infinite dilution limit [J].
Aubouy, M ;
Trizac, E ;
Bocquet, L .
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 2003, 36 (22) :5835-5840
[2]   Ionic condensation and charge renormalization in colloidal suspensions [J].
Belloni, L .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 140 (1-3) :227-243
[3]   WEAK POLYELECTROLYTES BETWEEN 2 SURFACES - ADSORPTION AND STABILIZATION [J].
BOHMER, MR ;
EVERS, OA ;
SCHEUTJENS, JMHM .
MACROMOLECULES, 1990, 23 (08) :2288-2301
[4]   Complexation of anionic polyelectrolytes with cationic liposomes: Evidence of reentrant condensation and lipoplex formation [J].
Bordi, F ;
Cametti, C ;
Diociaiuti, M ;
Gaudino, D ;
Gili, T ;
Sennato, S .
LANGMUIR, 2004, 20 (13) :5214-5222
[5]  
BORISOV OV, 1994, J PHYS II, V4, P913
[6]   Electrostatics of DNA cationic lipid complexes: isoelectric instability [J].
Bruinsma, R .
EUROPEAN PHYSICAL JOURNAL B, 1998, 4 (01) :75-88
[7]   DOTAP/DOPE and DC-Chol/DOPE lipoplexes for gene delivery: zeta potential measurements and electron spin resonance spectra [J].
Ciani, L ;
Ristori, S ;
Calamai, L ;
Martini, G .
BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES, 2004, 1664 (01) :70-79
[8]   The structure of DNA complexes with cationic liposomes - cylindrical or flat bilayers? [J].
Dan, N .
BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES, 1998, 1369 (01) :34-38
[9]   Mechanisms and kinetics of liposome-cell interactions [J].
Düzgünes, N ;
Nir, S .
ADVANCED DRUG DELIVERY REVIEWS, 1999, 40 (1-2) :3-18
[10]   Phospholipid liposomes stabilized by the coverage of polyelectrolyte [J].
Ge, LQ ;
Möhwald, H ;
Li, JB .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 221 (1-3) :49-53