Dynamic density functional study of a driven colloidal particle in polymer solutions

被引:57
作者
Penna, F [1 ]
Dzubiella, J
Tarazona, P
机构
[1] Univ Autonoma Madrid, Dept Fis Teor Mat Condensada, E-28049 Madrid, Spain
[2] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England
关键词
D O I
10.1103/PhysRevE.68.061407
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The dynamic density functional (DDF) theory and standard Brownian dynamics simulations (BDS) are used to study the drifting effects of a colloidal particle in a polymer solution, both for ideal and interacting polymers. The structure of the stationary density distributions and the total induced current are analyzed for different drifting rates. We find good agreement with the BDS, which gives support to the assumptions of the DDF theory. The qualitative aspect of the density distribution are discussed and compared to recent results for driven colloids in one-dimensional channels and to analytical expansions for the ideal solution limit.
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页数:5
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共 21 条
[11]   Effective interactions in soft condensed matter physics [J].
Likos, CN .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 2001, 348 (4-5) :267-439
[12]   Mean-field fluid behavior of the Gaussian core model [J].
Louis, AA ;
Bolhuis, PG ;
Hansen, JP .
PHYSICAL REVIEW E, 2000, 62 (06) :7961-7972
[13]   Can polymer coils be modeled as "soft colloids"? [J].
Louis, AA ;
Bolhuis, PG ;
Hansen, JP ;
Meijer, EJ .
PHYSICAL REVIEW LETTERS, 2000, 85 (12) :2522-2525
[14]   Dynamic density functional theory of fluids [J].
Marconi, UMB ;
Tarazona, P .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (16) :8032-8044
[15]   Dynamic density functional theory of fluids [J].
Marconi, UMB ;
Tarazona, P .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2000, 12 (8A) :A413-A418
[16]   Dynamic density functional theory for steady currents: Application to colloidal particles in narrow channels [J].
Penna, F ;
Tarazona, P .
JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (03) :1766-1776
[17]   Colloidal sedimentation (and filtration) [J].
Philipse, AP .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1997, 2 (02) :200-206
[18]   The physics of a model colloid-polymer mixture [J].
Poon, WCK .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (33) :R859-R880
[19]  
PUSEY PN, 1991, LES HOUCH S, V51, P763
[20]   PHASE-TRANSITIONS IN GAUSSIAN CORE SYSTEM [J].
STILLINGER, FH .
JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (10) :3968-3974