Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex

被引：43

作者：

Madine, JW ^{[1
]}

Wang, X ^{[1
]}

Widenhoefer, RA ^{[1
]}

机构：

[1] Duke Univ, PM Gross Chem Lab, Durham, NC 27708 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 03期

关键词：

D O I：

10.1021/ol006901u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A 1:1 mixture of the platinum phenanthroline complex (phen)PtMe2 and B(C6F5)(3) catalyzed the cyclization/hydrosilylation of functionalized 1,6-and 1,7-diynes to form silylated 1,2-dialkylidenecycloalkanes in good yield and with high Z-selectivity.

引用

页码：385 / 388

页数：4

共 35 条

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