Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids

被引：747

作者：

Parnham, Emily R. ^{[1
]}

Morris, Russell E. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStChem, St Andrews KY16 9ST, Fife, Scotland

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2007年 / 40卷 / 10期

关键词：

D O I：

10.1021/ar700025k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionothermal synthesis, the use of ionic liquids as both solvent and template (structure -directing agent), has been used to prepare zeolites and inorganic-organic hybrids such as metal-organic frameworks. The underlying properties of the ionothermal method are discussed, and it is compared with traditional hydrothermal preparative methods. The materials resulting from ionothermal synthesis are described, and any structural features that can be related to the ionic liquid used as the solvent are discussed. Future areas of potential interest are also considered.

引用

页码：1005 / 1013

页数：9

共 65 条

[11] AlMePO-beta: inclusion and thermal removal of structure directing agent and the topotactic reconstructive transformation to its polymorph AlMePO-alpha [J].

Carter, VJ ;

Wright, PA ;

Gale, JD ;

Morris, RE ;

Sastre, E ;

PerezPariente, J .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (11) :2287-2292

[12] Structural diversity and chemical trends in hybrid inorganic-organic framework materials [J].

Cheetham, Anthony K. ;

Rao, C. N. R. ;

Feller, Russell K. .

CHEMICAL COMMUNICATIONS, 2006, (46) :4780-4795

[13] Confined rapid thermolysis/FTIR/ToF studies of imidazolium-based ionic liquids [J].

Chowdhury, A ;

Thynell, ST .

THERMOCHIMICA ACTA, 2006, 443 (02) :159-172

[14]

Cooper ER, 2005, STUD SURF SCI CATAL, V158, P247

[15] Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J].

Cooper, ER ;

Andrews, CD ;

Wheatley, PS ;

Webb, PB ;

Wormald, P ;

Morris, RE .

NATURE, 2004, 430 (7003) :1012-1016

[16] Phase transition and decomposition temperatures, heat capacities and viscosities of pyridinium ionic liquids [J].

Crosthwaite, JM ;

Muldoon, MJ ;

Dixon, JK ;

Anderson, JL ;

Brennecke, JF .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (06) :559-568

[17] The hydrothermal synthesis of zeolites: History and development from the earliest days to the present time [J].

Cundy, CS ;

Cox, PA .

CHEMICAL REVIEWS, 2003, 103 (03) :663-701

[18] ZEOLITE AND MOLECULAR-SIEVE SYNTHESIS [J].

DAVIS, ME ;

LOBO, RF .

CHEMISTRY OF MATERIALS, 1992, 4 (04) :756-768

[19] Ordered porous materials for emerging applications [J].

Davis, ME .

NATURE, 2002, 417 (6891) :813-821

[20] On the structure and dynamics of ionic liquids [J].

Del Pópolo, MG ;

Voth, GA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (05) :1744-1752

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