Advances in Li-S batteries

被引:1729
作者
Ji, Xiulei [1 ]
Nazar, Linda F. [1 ]
机构
[1] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
RECHARGEABLE LITHIUM BATTERIES; COMPOSITE CATHODE MATERIALS; IONIC LIQUID ELECTROLYTE; SULFUR CATHODE; ELECTROCHEMICAL PROPERTIES; POLYMER ELECTROLYTES; CARBON COMPOSITES; CELL ELECTROLYTE; GELATIN BINDER; CYCLE PROPERTY;
D O I
10.1039/b925751a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rechargeable Li-S batteries have received ever-increasing attention recently due to their high theoretical specific energy density, which is 3 to 5 times higher than that of Li ion batteries based on intercalation reactions. Li-S batteries may represent a next-generation energy storage system, particularly for large scale applications. The obstacles to realize this high energy density mainly include high internal resistance, self-discharge and rapid capacity fading on cycling. These challenges can be met to a large degree by designing novel sulfur electrodes with "smart'' nanostructures. This highlight provides an overview of major developments of positive electrodes based on this concept.
引用
收藏
页码:9821 / 9826
页数:6
相关论文
共 70 条
  • [1] LOW-TEMPERATURE NA-S BATTERY INCORPORATING A SOLUBLE-S CATHODE
    ABRAHAM, KM
    RAUH, RD
    BRUMMER, SB
    [J]. ELECTROCHIMICA ACTA, 1978, 23 (06) : 501 - 507
  • [2] On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries
    Aurbach, Doron
    Pollak, Elad
    Elazari, Ran
    Salitra, Gregory
    Kelley, C. Scordilis
    Affinito, John
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (08) : A694 - A702
  • [3] Rechargeable lithium sulfur battery - I. Structural change of sulfur cathode during discharge and charge
    Cheon, SE
    Ko, KS
    Cho, JH
    Kim, SW
    Chin, EY
    Kim, HT
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) : A796 - A799
  • [4] Choi JW, 2006, J IND ENG CHEM, V12, P939
  • [5] Electrochemical properties of sulfur electrode containing nano Al2O3 for lithium/sulfur cell
    Choi, Y. J.
    Jung, B. S.
    Lee, D. J.
    Jeong, J. H.
    Kim, K. W.
    Ahn, H. J.
    Cho, K. K.
    Gu, H. B.
    [J]. PHYSICA SCRIPTA, 2007, T129 : 62 - 65
  • [6] Effects of carbon coating on the electrochemical properties of sulfur cathode for lithium/sulfur cell
    Choi, Young-Jin
    Chung, Young-Dong
    Baek, Chang-Yong
    Kim, Ki-Won
    Ahn, Hyo-Jun
    Ahn, Jou-Hyeon
    [J]. JOURNAL OF POWER SOURCES, 2008, 184 (02) : 548 - 552
  • [7] Improvement of cycle property of sulfur electrode for lithium/sulfur battery
    Choi, Young-Jin
    Kim, Ki-Won
    Ahn, Hyo-Jun
    Ahn, Jou-Hyeon
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 449 (1-2) : 313 - 316
  • [8] Chu M. Y., 1997, US Patent, Patent No. [US 5686201, 5686201]
  • [9] De Jonghe L. C., 1990, U. S. Patent, Patent No. [4,917,974, 4917974]
  • [10] DEAN JA, 1985, LANGES HDB CHEM, P3