Advances in Li-S batteries

被引:1729
作者
Ji, Xiulei [1 ]
Nazar, Linda F. [1 ]
机构
[1] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
RECHARGEABLE LITHIUM BATTERIES; COMPOSITE CATHODE MATERIALS; IONIC LIQUID ELECTROLYTE; SULFUR CATHODE; ELECTROCHEMICAL PROPERTIES; POLYMER ELECTROLYTES; CARBON COMPOSITES; CELL ELECTROLYTE; GELATIN BINDER; CYCLE PROPERTY;
D O I
10.1039/b925751a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rechargeable Li-S batteries have received ever-increasing attention recently due to their high theoretical specific energy density, which is 3 to 5 times higher than that of Li ion batteries based on intercalation reactions. Li-S batteries may represent a next-generation energy storage system, particularly for large scale applications. The obstacles to realize this high energy density mainly include high internal resistance, self-discharge and rapid capacity fading on cycling. These challenges can be met to a large degree by designing novel sulfur electrodes with "smart'' nanostructures. This highlight provides an overview of major developments of positive electrodes based on this concept.
引用
收藏
页码:9821 / 9826
页数:6
相关论文
共 70 条
  • [51] Effects of nanosized adsorbing material on electrochemical properties of sulfur cathodes for Li/S secondary batteries
    Song, MS
    Han, SC
    Kim, HS
    Kim, JH
    Kim, KT
    Kang, YM
    Ahn, HJ
    Dou, SX
    Lee, JY
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (06) : A791 - A795
  • [52] Application of gelatin as a binder for the sulfur cathode in lithium-sulfur batteries
    Sun, Jing
    Huang, Yaqin
    Wang, Weikun
    Yu, Zhongbao
    Wang, Anbang
    Yuan, Keguo
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (24) : 7084 - 7088
  • [53] Preparation and electrochemical characterization of the porous sulfur cathode using a gelatin binder
    Sun, Jing
    Huang, Yaqin
    Wang, Weikun
    Yu, Zhongbao
    Wang, Anbang
    Yuan, Keguo
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (06) : 930 - 933
  • [54] Visco S. J., 2001, U.S. Pat, Patent No. [6 210 832, 6210832]
  • [55] Visco S.J., 2007, US Patent, Patent No. [7,282,302, 7282302]
  • [56] Sulfur-mesoporous carbon composites in conjunction with a novel ionic liquid electrolyte for lithium rechargeable batteries
    Wang, J.
    Chew, S. Y.
    Zhao, Z. W.
    Ashraf, S.
    Wexler, D.
    Chen, J.
    Ng, S. H.
    Chou, S. L.
    Liu, H. K.
    [J]. CARBON, 2008, 46 (02) : 229 - 235
  • [57] Sulphur-polypyrrole composite positive electrode materials for rechargeable lithium batteries
    Wang, J.
    Chen, J.
    Konstantinov, K.
    Zhao, L.
    Ng, S. H.
    Wang, G. X.
    Guo, Z. P.
    Liu, H. K.
    [J]. ELECTROCHIMICA ACTA, 2006, 51 (22) : 4634 - 4638
  • [58] Sulfur composite cathode materials for rechargeable lithium batteries
    Wang, JL
    Yang, J
    Wan, CR
    Du, K
    Xie, JY
    Xu, NX
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (06) : 487 - 492
  • [59] Polymer lithium cells with sulfur composites as cathode materials
    Wang, JL
    Liu, L
    Ling, ZJ
    Yang, J
    Wan, CR
    Jiang, CY
    [J]. ELECTROCHIMICA ACTA, 2003, 48 (13) : 1861 - 1867
  • [60] Wang JL, 2002, ADV MATER, V14, P963, DOI 10.1002/1521-4095(20020704)14:13/14<963::AID-ADMA963>3.0.CO