Flash vacuum pyrolysis of stabilised phosphorus ylides.: Part 13.: Extrusion of Ph3P from sulfinyl ylides and reactivity of the resulting sulfinyl carbenes

被引：13

作者：

Aitken, RA ^{[1
]}

Drysdale, MJ ^{[1
]}

Ryan, BM ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 20期

关键词：

D O I：

10.1039/a806182c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six alpha-sulfiliyl phosphorus ylides 6 have been prepared and are found upon flash vacuum pyrolysis at 500 degrees C to undergo mainly extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arylsufinyl ylides loss of Ph3PO to give additional products is also observed.

引用

页码：3345 / 3348

页数：4

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