FLASH VACUUM PYROLYSIS OF SULFINYL STABILIZED PHOSPHORUS YLIDES - GENERATION AND REACTIVITY OF SULFINYLCARBENES

被引：11

作者：

AITKEN, RA

DRYSDALE, MJ

RYAN, BM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 22期

关键词：

D O I：

10.1039/c39930001699

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flash vacuum pyrolysis of alpha-alkanesulfinyl phosphorus ylides results mainly in extrusion of Ph3P to give thioesters, presumably by 1,2-oxygen transfer in the initially formed sulfinyl carbenes; for alpha-arenesulfinyl ylides loss of Ph3PO to give additional products is also observed.

引用

页码：1699 / 1700

页数：2

共 31 条

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