Short-circuit current density improvement of inverted polymer solar cells using PbPc to enhance photon absorption over 600 nm

被引:18
作者
Shen, Liang [1 ]
Xu, Yang [1 ]
Zhang, Xindong [1 ]
Meng, Fanxu [1 ]
Ruan, Shengping [1 ]
Chen, Weiyou [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
Tandem; Inverted; PbPc; Photon absorption; OXIDE;
D O I
10.1016/j.solmat.2010.08.017
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
We demonstrate a type of inverted polymer solar cells with the structure of indium tin oxide (ITO)/titanium dioxide (TiO2)/regioregular poly-(3-hexylthiophene; RR-P3HT): [6,6]-phenyl C-60 butyric acid methyl ester (PCBM)/lead phthalocyanine (PbPc)/Molybdenum trioxide(MoO3)/Ag PbPc, which is well known as a p type material, has a strong absorption from 600-800 nm, where large numbers of photons exist in AM 1.5 radiation. It is found that the bulk heterojunction of P3HT:PCBM and the bilayer heterojunction of PCBM/PbPc existed simultaneously, and the two solar cells are parallel. The short-circuit current density with PbPc is dramatically improved compared with that without PbPc. We attribute this improvement to fabricating the tandem solar cells. The photon absorption is significantly enhanced due to introduction of PbPc. The thickness dependence of PbPc on the device performance is investigated in detail. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2451 / 2454
页数:4
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