Short-circuit current density improvement of inverted polymer solar cells using PbPc to enhance photon absorption over 600 nm

被引:18
作者
Shen, Liang [1 ]
Xu, Yang [1 ]
Zhang, Xindong [1 ]
Meng, Fanxu [1 ]
Ruan, Shengping [1 ]
Chen, Weiyou [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
Tandem; Inverted; PbPc; Photon absorption; OXIDE;
D O I
10.1016/j.solmat.2010.08.017
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
We demonstrate a type of inverted polymer solar cells with the structure of indium tin oxide (ITO)/titanium dioxide (TiO2)/regioregular poly-(3-hexylthiophene; RR-P3HT): [6,6]-phenyl C-60 butyric acid methyl ester (PCBM)/lead phthalocyanine (PbPc)/Molybdenum trioxide(MoO3)/Ag PbPc, which is well known as a p type material, has a strong absorption from 600-800 nm, where large numbers of photons exist in AM 1.5 radiation. It is found that the bulk heterojunction of P3HT:PCBM and the bilayer heterojunction of PCBM/PbPc existed simultaneously, and the two solar cells are parallel. The short-circuit current density with PbPc is dramatically improved compared with that without PbPc. We attribute this improvement to fabricating the tandem solar cells. The photon absorption is significantly enhanced due to introduction of PbPc. The thickness dependence of PbPc on the device performance is investigated in detail. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2451 / 2454
页数:4
相关论文
共 22 条
[11]   Fabrication and processing of polymer solar cells: A review of printing and coating techniques [J].
Krebs, Frederik C. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (04) :394-412
[12]   Small bandgap polymers for organic solar cells (polymer material development in the last 5 years) [J].
Kroon, Renee ;
Lenes, Martijn ;
Hummelen, Jan C. ;
Blom, Paul W. M. ;
De Boer, Bert .
POLYMER REVIEWS, 2008, 48 (03) :531-582
[13]   Bulk heterojunction organic photovoltaic cell fabricated with a p-type conjugated star-shaped molecule [J].
Lee, Tae Wan ;
Kim, Dae Cheol ;
Kang, Nam Su ;
Yu, Jae Woong ;
Cho, Min Ju ;
Kim, Kyung Hwan ;
Choi, Dong Hoon .
CHEMISTRY LETTERS, 2008, 37 (08) :866-867
[14]   High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].
Li, G ;
Shrotriya, V ;
Huang, JS ;
Yao, Y ;
Moriarty, T ;
Emery, K ;
Yang, Y .
NATURE MATERIALS, 2005, 4 (11) :864-868
[15]   Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties [J].
Liang, Yongye ;
Feng, Danqin ;
Wu, Yue ;
Tsai, Szu-Ting ;
Li, Gang ;
Ray, Claire ;
Yu, Luping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7792-7799
[16]   Bulk heterojunction solar cells with internal quantum efficiency approaching 100% [J].
Park, Sung Heum ;
Roy, Anshuman ;
Beaupre, Serge ;
Cho, Shinuk ;
Coates, Nelson ;
Moon, Ji Sun ;
Moses, Daniel ;
Leclerc, Mario ;
Lee, Kwanghee ;
Heeger, Alan J. .
NATURE PHOTONICS, 2009, 3 (05) :297-U5
[17]   Small molecular weight organic thin-film photodetectors and solar cells [J].
Peumans, P ;
Yakimov, A ;
Forrest, SR .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (07) :3693-3723
[18]   Organic solar cells with sensitivity extending into the near infrared - art. no. 200508 [J].
Rand, BP ;
Xue, JG ;
Yang, F ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 2005, 87 (23) :1-3
[19]   Performance improvement of TiO2/P3HT solar cells using CuPc as a sensitizer [J].
Shen, Liang ;
Zhu, Guohui ;
Guo, Wenbin ;
Tao, Chen ;
Zhang, Xindong ;
Liu, Caixia ;
Chen, Weiyou ;
Ruan, Shengping ;
Zhong, Zhicheng .
APPLIED PHYSICS LETTERS, 2008, 92 (07)
[20]   Accurate measurement and characterization of organic solar cells [J].
Shrotriya, Vishal ;
Li, Gang ;
Yao, Yan ;
Moriarty, Tom ;
Emery, Keith ;
Yang, Yang .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (15) :2016-2023