In situ observation on Au(100) surface in molten EMImBF4 by electrochemical atomic force microscopy (EC-AFM)

被引：15

作者：

Kubo, K ^{[1
]}

Hirai, N ^{[1
]}

Tanaka, T ^{[1
]}

Hara, S ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat Sci & Proc, Suita, Osaka 5650871, Japan

来源：

SURFACE SCIENCE | 2003年 / 546卷 / 01期

关键词：

surface structure; morphology; roughness; and topography; gold; atomic force microscopy;

D O I：

10.1016/j.susc.2003.08.034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Au(1 0 0) surface structure in contact with 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF(4)) has been observed using electrochemical atomic force microscopy (EC-AFM) under an electrochemically controlled potential. The AFM images, taken in EMImBF(4) in the potential range from -0.6 to 0.2 V vs. Ag/Ag(I), shows a fourfold symmetry with the distance between protrusions of approximate to0.30-0.32 nm. This structure agrees well with the ideal surface structure of Au(1 0 0)-(1 x 1) and it is very similar to that previously obtained in a sulfuric acid aqueous solution. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：L785 / L788

页数：4

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