Piperazinium aquabis(oxalato) oxidovanadate(IV) dihydrate

被引：11

作者：

Aghabozorg, Hossein

Motyeian, Elham

Aghajani, Zahra

Ghadermazi, Mohammad

Gharamaleki, Jafar Attar

机构：

[1] Teacher Training Univ, Dept Chem, Tehran 15614, Iran

[2] Islamic Azad Univ, Dept Chem, Qom Branch, Tehran, Iran

[3] Kurdistan Univ, Fac Sci, Dept Chem, Sanandaj, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807023616

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, (C(4)H(12)N(2))[V(C(2)O(4))(2)O(H(2)O)] center dot 2H(2)O, has been obtained by the reaction of vanadium( III) chloride with piperazinediium oxalate in aqueous solution. It shows distorted octahedral geometry [ V=O =1.6010 ( 12) angstrom and V - O = 1.9932 ( 12) - 2.2176 ( 12) A]]. The structure exhibits intermolecular N - H center dot center dot center dot O and C - H center dot center dot center dot O hydrogen bonds. The uncoordinated water molecules contribute to the formation of the supramolecular structure via O - H center dot center dot center dot O hydrogen bonds.

引用

页码：M1754 / U1527

页数：12

共 8 条

[1] 2,6-Diaminopyridinium pyridinium-2,6-dicarboxylate: a redetermination [J].

Aghabozorg, H ;

Saei, AA ;

Ramezanipour, F .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :O3242-O3244

[2] 2,9-Dimethyl-1,10-phenanthrolinium dioxido(pyridine-2,6-dicarboxylato)vanadate(V) monohydrate [J].

Aghabozorg, Hossein ;

Sadr-Khanlou, Elahe .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M1753-U1515

[3]

Bruker, 2005, APEX2

[4] Piperazinium aquabis(oxalato)oxovanadate(IV) sesquihydrate [J].

Lin, L ;

Wu, SF ;

Huang, CC ;

Zhang, HH ;

Huang, XH ;

Lian, ZX .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M631-M633

[5] A novel proton transfer compound containing 2,6-pyridinedicarboxylic acid and creatinine and its zinc(II) complex - Synthesis, characterization, crystal structure, and solution studies [J].

Moghimi, A ;

Sharif, MA ;

Shokrollahi, A ;

Shamsipur, M ;

Aghabozorg, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (05) :902-908

[6]

RANJBAR M, 2004, ANAL SCI, V20, pX135

[7]

Sheldrick G.M., 1998, SHELXTL VERSION 5 10

[8]

Soleimannejad J., 2005, ANAL SCI, V21, px49, DOI DOI 10.2116/analsci.21.49

← 1 →