Pd nanoparticles supported on N-doped nanocarbon for the direct synthesis of H2O2 from H2 and O2

被引：83

作者：

Abate, S. ^{[1
]}

Arrigo, R. ^{[2
]}

Schuster, M. E. ^{[2
]}

Perathoner, S. ^{[1
]}

Centi, G. ^{[1
]}

Villa, A. ^{[2
]}

Su, D. ^{[2
]}

Schlogl, R. ^{[2
]}

机构：

[1] Univ Messina, Dipartimento Chim Ind & Ingn Mat INSTM UdR Messi, I-98166 Messina, Italy

[2] Fritz Haber Inst Max Planck Gesell, Dept Inorgan Chem, Berlin, Germany

来源：

CATALYSIS TODAY | 2010年 / 157卷 / 1-4期

关键词：

Hydrogen peroxide; Pd; Nanocarbon; CNT like; H2O2 direct synthesis; CATALYTIC MEMBRANES; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; AU;

D O I：

10.1016/j.cattod.2010.01.027

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Pd nanoparticles deposited by sot-immobilization on N-doped nanocarbon are studied in the direct synthesis of H2O2 and compared with undoped catalysts or prepared by the same Pd deposition method on active carbon (Vulcan XC-72) The Pd on N-CNT-like gives high productivities to H2O2 comparable to the best literature results The introducing of nitrogen in the CNT-like material favors not only the dispersion of Pd (with a consequent improvement of the activity) but also the specific turnover However the introduction of these N functionalities on the surface has also a negative effect on the rate of H2O2 consecutive conversion to water (C) 2010 Elsevier B V All rights reserved

引用

页码：280 / 285

页数：6

共 20 条

[1] Performances of Pd-Me (Me = Ag, Pt) catalysts in the direct synthesis of H2O2 on catalytic membranes [J].