One-step H2O2 and phenol syntheses: Examples of challenges for new sustainable selective oxidation processes

被引：63

作者：

Centi, Gabriele

Perathoner, Siglinda ^{[1
]}

机构：

[1] Univ Messina, Dept Ind Chem & Engn Mat, I-98166 Messina, Italy

来源：

CATALYSIS TODAY | 2009年 / 143卷 / 1-2期

关键词：

H2O2; Phenol; Selective oxidation; TS-1; Pd-membrane; CO2-expanded solvents; HYDROGEN-PEROXIDE SYNTHESIS; OXIDE CATALYSTS; BENZENE; HYDROXYLATION; CHEMISTRY; GREEN; PERFORMANCE; KINETICS; O-2; H-2;

D O I：

10.1016/j.cattod.2008.09.032

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Selected results Which Outline issues and perspectives on the direct synthesis of H2O2 from H-2/O-2 and of phenol by benzene hydroxylation with H2O2, as examples of the challenges for new sustainable selective oxidation processes, are presented after an introduction oil the industrial context underlying the motivations to develop these reactions. It is shown how they combine a lower impacton the environment and meet together demand and process economics opportunities giving a chance for innovation not only limited to a chemical production context, e.g. they are an interesting example of trends for a sustainable chemical production. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：145 / 150

页数：6

共 43 条

[1] The issue of selectivity in the direct synthesis of H2O2 from H2 and O2:: the role of the catalyst in relation to the kinetics of reaction [J].