Direct synthesis of hydrogen peroxide solution with palladium-loaded sulfonic acid polystyrene resins

被引：102

作者：

Blanco-Brieva, G ^{[1
]}

Cano-Serrano, E ^{[1
]}

Campos-Martin, JM ^{[1
]}

Fierro, JLG ^{[1
]}

机构：

[1] CSIC, Inst Catalisis & Petroleoquim, Madrid 28049, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 10期

关键词：

D O I：

10.1039/b402530j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anchorage of Pd-II ions into mesoporous ion-exchange resins functionalized with sulfonic groups is highly effective for the direct synthesis of hydrogen peroxide using methanol as a solvent at 313 K. The high performance of these catalytic systems is due to the ability of sulfonic acid groups of the resin to interact and stabilize Pd-II ions without further reduction to metallic palladium, as revealed by photo-electron spectroscopy.

引用

页码：1184 / 1185

页数：2

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