Simultaneous determination of anthraquinones, their 8-β-D-glucosides, and sennosides of Rhei rhizoma by capillary electrophoresis

被引：18

作者：

Koyama, J ^{[1
]}

Morita, I ^{[1
]}

Fujiyoshi, H ^{[1
]}

Kobayashi, N ^{[1
]}

机构：

[1] Kobe Pharmaceut Univ, Higashinada Ku, Kobe, Hyogo 6588558, Japan

来源：

CHEMICAL & PHARMACEUTICAL BULLETIN | 2005年 / 53卷 / 05期

关键词：

cyclodextrin modified capillary zone electrophoresis; emodin; chrysophanol; rhein; sennoside; anthraquinone glucoside;

D O I：

10.1248/cpb.53.573

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The simultaneous separation and determination of major anthraquinones (emodin, chrysophanol, rhein and their glucosides, aloe-emodin, sennoside A, and sennoside B) of Rhei Rhizoma were achieved by cyclodextrin modified capillary zone electrophoresis. The running electrolyte used in this method was 0.005 M alpha-cyclodextrin in 0.03 M borate buffer (pH 10.0) containing 20% acetonitrile, with an applied voltage of 20 kV.

引用

页码：573 / 575

页数：3

共 25 条

[1] DIE STELLUNG DER GLUCOSE IN SYNTHETISCH HERGESTELLTEM CHRYSOPHANOL-GLUCOSID [J].

BELLAART, AC .

CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (08) :2471-&

[2]

Birks J.W., 1982, TRAC TRENDS ANAL CHE, V1, P361

[3]

HORHAMMER L, 1964, NATURWISSENSCHAFTEN, V51, P310

[4]

KASHIWADA Y, 1989, CHEM PHARM BULL, V37, P999, DOI 10.1248/cpb.37.999

[5]

Koyama J, 2003, CHEM PHARM BULL, V51, P418, DOI 10.1248/cpb.51.418

[6]

Koyama J, 1997, PHYTOCHEM ANALYSIS, V8, P135, DOI 10.1002/(SICI)1099-1565(199705)8:3<135::AID-PCA343>3.3.CO

[7]

2-M

[8] Capillary electrophoresis of Anthraquinones from Cassia siamea [J].

Koyama, J ;

Morita, I ;

Tagahara, K ;

Bakari, J ;

Aqil, M .

CHEMICAL & PHARMACEUTICAL BULLETIN, 2002, 50 (08) :1103-1105

[9]

KOYAMA J, 1997, PHYTOCHEMISTRY, V56, P849

[10] BORATE COMPLEXATION OF FLAVONOID-O-GLYCOSIDES IN CAPILLARY ELECTROPHORESIS .2. SEPARATION OF FLAVONOID-3-O-GLYCOSIDES DIFFERING IN THEIR SUGAR MOIETY [J].

MORIN, P ;

VILLARD, F ;

DREUX, M ;

ANDRE, P .

JOURNAL OF CHROMATOGRAPHY, 1993, 628 (01) :161-169

← 1 2 3 →