Reduced graphene oxide/tin oxide composite as an enhanced anode material for lithium ion batteries prepared by homogenous coprecipitation

被引:142
作者
Zhu, Xianjun [1 ,2 ,3 ]
Zhu, Yanwu [1 ,2 ]
Murali, Shanthi [1 ,2 ]
Stoller, Meryl D. [1 ,2 ]
Ruoff, Rodney S. [1 ,2 ]
机构
[1] Univ Texas Austin, Dept Mech Engn, Austin, TX 78712 USA
[2] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
[3] Cent China Normal Univ, Coll Chem, Wuhan 430079, Hubei, Peoples R China
基金
美国国家科学基金会;
关键词
Reducul graphene oxide; Tin oxide; Homogeneous coprecipitation; Lithium ion battery; Anode; SN-C COMPOSITE; IRREVERSIBLE CAPACITIES; TIN; ELECTRODE; PERFORMANCE; STABILITY; HYBRID;
D O I
10.1016/j.jpowsour.2011.04.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Reduced graphene oxide/tin oxide composite is prepared by homogenous coprecipitation. Characterizations show that tin oxide particles are anchored uniformly on the surface of reduced graphene oxide platelets. As an anode material for Li ion batteries, it has 2140 mAh g(-1) and 1080 mAh g(-1) capacities for the first discharge and charge, respectively, which is more than the theoretical capacity of tin oxide, and has good capacity retention with a capacity of 649 mAh g(-1) after 30 cycles. The simple synthesis method can be readily adapted to prepare other composites containing reduced graphene oxide as a conducting additive that, in addition to supporting metal oxide nanoparticles, can also provide additional Li binding sites to, perhaps, further enhance capacity. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:6473 / 6477
页数:5
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