Unusual parallel and inclined interlocking modes in polyrotaxane-like metal-organic frameworks

被引:220
作者
Yang, Jin [1 ]
Ma, Jian-Fang [1 ]
Batten, Stuart R. [2 ]
Su, Zhong-Min [1 ]
机构
[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate, Changchun 130024, Peoples R China
[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
关键词
D O I
10.1039/b800199e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We describe here two unusual polyrotaxane-like metal-organic frameworks of [Co(2)(1,3-bix)(2)(bpea)(2)] 1 and [Cd(4)(1,4-bix)(4)(bpea)(4)] center dot 4H(2)O 2, where both species contain loops and rods that are interlaced in a highly rare "parallel'' fashion in 1, but, uniquely, in an "inclined'' fashion in 2.
引用
收藏
页码:2233 / 2235
页数:3
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