Lewis acid-catalyzed hydrogenation:: B(C6F5)3-mediated reduction of imines and nitriles with H2

被引：365

作者：

Chase, Preston A. ^{[1
]}

Jurca, Titel ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 14期

关键词：

D O I：

10.1039/b718598g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Lewis acid B(C6F5)(3) has been found to be an efficient catalyst for the direct hydrogenation of imines and the reductive ring-opening of aziridines with H-2 under mild conditions; addition of a bulky phosphine allows for the reduction of protected nitriles.

引用

页码：1701 / 1703

页数：3

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