Flexible molecules with defined shape .5. Conformational analysis of 2,4,6,n-polymethylated alkane derivatives

被引：10

作者：

Gottlich, R ^{[1
]}

Facke, T ^{[1
]}

Rolle, U ^{[1
]}

Hoffmann, RW ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1996年 / 10期

关键词：

D O I：

10.1039/p29960002059

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Poly-2,4,6,n-methylated undecene-(3-6) and pentadecene-derivatives (8-11) have been synthesized. In these compounds each backbone segment displays local bi-conformational behaviour. The effect of oxygen-substituents on the conformer population of the individual backbone segments has been studied by evaluating (3)J(H,H) and (3)J(C,C) coupling constants.

引用

页码：2059 / 2063

页数：5

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