Sorption and redox processes controlling transport in a stream impacted by acid arsenic fate and mine drainage

Reigous acid creek originating from the Camoules tailings impoundment supplies high concentrations of arsenic under soluble (up to similar to 4 mg/l) and particulate (up to 150 mgAs/g) phases to the Amous river, situated at the drainage basin of the Rh6ne river (Southern France). The metalloid is present as As(III) (> 95%) in Reigous creek water while As(V) predominates (50-80%) in the solid phase, i.e. schwertmannite. At the confluence between acid (pH < 5) creek and alkaline Amous river, As(III) concentrations decrease ten-fold through dilution and formation of As-rich ferrihydrite (As/Fe=0.02-0.1) containing 10-30% As(III). However, these attenuation processes are not efficient in the summer heatwave of 2003 since As concentrations in Amous river water (>= 20 mu g/l) and As/Fe ratios in particulate matter (>= 0.07) are closed to those of Reigous creek (:522 mu g/l and <= 0.02, respectively) or even higher. Downstream the confluence, processes involved in the transport of aqueous As along Amous river flowpath vary seasonally. Arsenic is transported conservatively in the aqueous phase away from the confluence in the cooler months; thus, dilution by unpolluted tributaries is the only process that decreases As concentrations. However, As(III) is rapidly oxidized and As(V) remains in solution. In contrast, during the warm season, desorption from As-rich sediment occurs which results in an increase of As(V) and As(III) concentrations along Amous river flow until they reach up to similar to 20 mu g/l each. Therefore, Amous river seems not to be totally recovered from mine-related arsenic contamination after 3.5 km and may affect freshwater resources further downstream. (c) 2004 Elsevier B.V. All rights reserved.