Evaporation after ionization in molecular clusters:: application to 1-naphthol-(NH3)n

被引:29
作者
Dedonder-Lardeux, C [1 ]
Grosswasser, D [1 ]
Jouvet, C [1 ]
Martrenchard, S [1 ]
Teahu, A [1 ]
机构
[1] Univ Paris 11, CNRS, Photophys Mol Lab, F-91405 Orsay, France
关键词
D O I
10.1039/b104836h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Evaporation after ionization in clusters has been studied in the case. From this study, it 1-naphthol-(NH3)(n) appears that, for n greater than or equal to 3, all clusters evaporate at least one ammonia molecule in the excitation and/or ionization processes. This leads to the conclusion that the ground state proton transfer occurs in clusters with n greater than or equal to 6, and if there is an excited state proton transfer, it occurs only at n = 5.
引用
收藏
页码:4316 / 4324
页数:9
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