Palladium-catalyzed hydrophosphorylation of 1,3-dienes leading to allylphosphonates

被引：54

作者：

Mirzaei, F ^{[1
]}

Han, LB ^{[1
]}

Tanaka, M ^{[1
]}

机构：

[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 02期

关键词：

addition reactions; catalysis; dienes; hydrophosphorylation; palladium;

D O I：

10.1016/S0040-4039(00)01928-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed 1,4-hydrophosphorylation of 1,3-dienes efficiently takes place with 4,4,5,5-tetramethyl-1,3,2-dioxaphospholane 2-oxide HP(O)(OCMe2CMe2O) to afford the corresponding allylphosphonates selectively in high yields. Mechanistic studies have revealed that the reaction proceeds through addition of intermediate H-Pd species to 1,3-diene generating a pi -allylpalladium complex, which affords the adduct via subsequent reductive elimination. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：297 / 299

页数：3

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