Indium-mediated regioselective allylation of terminal epoxides: a facile synthesis of bishomoallyl alcohols

被引：30

作者：

Yadav, JS ^{[1
]}

Anjaneyulu, S ^{[1
]}

Ahmed, MM ^{[1
]}

Reddy, BVS ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 13期

关键词：

epoxides; indium metal; allyl bromide; unsaturated alcohols;

D O I：

10.1016/S0040-4039(01)00112-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allyl indium, prepared from allyl bromide and indium metal in THF, reacts with terminal epoxides at room temperature to afford the corresponding bishomoallyl alcohols in excellent yields and with good regioselectivity. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2557 / 2559

页数：3

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