Synthesis, reaction, and recycle of light fluorous Grubbs-Hoveyda catalysts for alkene metathesis

被引：124

作者：

Matsugi, M ^{[1
]}

Curran, DP ^{[1
]}

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 05期

关键词：

D O I：

10.1021/jo048001n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Light fluorous versions of first- and second-generation Grubbs-Hoveyda metathesis catalysts are introduced. These exhibit the expected reactivity profile, are readily recovered from reaction mixtures by fluorous solid-phase extraction, and can be routinely reused five or more times. The catalysts can be used in a stand alone fashion, or supported on fluorous silica gel.

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收藏

页码：1636 / 1642

页数：7

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