Separation, recovery and recycling of a fluorous-tagged nickel catalyst using fluorous solid-phase extraction

被引:38
作者
Croxtall, B [1 ]
Hope, EG [1 ]
Stuart, AM [1 ]
机构
[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
关键词
D O I
10.1039/b308543k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly efficient separation, recovery and recycling of the fluorous-tagged catalyst, [Ni{F13C6C(O)CHC(O)C6F13)(2)], can be achieved with fluorous solid-phase extraction, after the Lewis acid catalysed synthesis of enaminodiones in conventional organic solvents.
引用
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页码:2430 / 2431
页数:2
相关论文
共 18 条
[1]   Wacker oxidation of alkenes using a fluorous biphasic system. A mild preparation of polyfunctional ketones [J].
Betzemeier, B ;
Lhermitte, F ;
Knochel, P .
TETRAHEDRON LETTERS, 1998, 39 (37) :6667-6670
[2]   Synthesis and coordination chemistry of perfluoroalkyl-derivatised β-diketonates [J].
Croxtall, B ;
Fawcett, J ;
Hope, EG ;
Stuart, AM .
JOURNAL OF FLUORINE CHEMISTRY, 2003, 119 (01) :65-73
[3]  
Curran DP, 2001, SYNLETT, P1488
[4]   Fluorous synthesis with fewer fluorines (light fluorous synthesis): separation of tagged from untagged products by solid-phase extraction with fluorous reverse-phase silica gel [J].
Curran, DP ;
Luo, ZY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (39) :9069-9072
[5]   Fluorous phase separation techniques in catalysis [J].
de Wolf, E ;
van Koten, G ;
Deelman, BJ .
CHEMICAL SOCIETY REVIEWS, 1999, 28 (01) :37-41
[6]   Fluorous biphase catalysis [J].
Hope, EG ;
Stuart, AM .
JOURNAL OF FLUORINE CHEMISTRY, 1999, 100 (1-2) :75-83
[7]   FACILE CATALYST SEPARATION WITHOUT WATER - FLUOROUS BIPHASE HYDROFORMYLATION OF OLEFINS [J].
HORVATH, IT ;
RABAI, J .
SCIENCE, 1994, 266 (5182) :72-75
[8]   Fluorous biphase chemistry [J].
Horváth, IT .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (10) :641-650
[9]  
Ishihara K, 2002, SYNLETT, P1299
[10]  
Ishihara K, 2001, SYNLETT, P1371