Raman scattering study of electrochemically doped single wall nanotubes

被引:32
作者
An, CP [1 ]
Vardeny, ZV
Iqbal, Z
Spinks, G
Baughman, RH
Zakhidov, A
机构
[1] Univ Utah, Dept Phys, Salt Lake City, UT 84112 USA
[2] Honeywell Inc, Res & Technol Ctr, Morristown, NJ 07962 USA
关键词
carbon nanotubes; graphite and related compounds; Raman scattering spectroscopy; electrochemical intercalation;
D O I
10.1016/S0379-6779(00)00448-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sheets of single wall carbon nanotubes (SWNT) bundles were studied by Raman scattering spectroscopy when doped electrochemically in an aqueous NaCl solution. At non-resonant conditions, the radial breathing mode (RBM) and tangential displacement modes (TDM) change very little intensity and frequency with electrochemical doping. Resonant Raman scattering for the TDM band, however, show large changes when applying or negative voltages. We conclude that the electronic resonance condition disappears due to larger change of the electronic occupancy with electrochemical doping. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:411 / 414
页数:4
相关论文
共 11 条
[1]   Resonant Raman study of the structure and electronic properties of single-wall carbon nanotubes [J].
Alvarez, L ;
Righi, A ;
Guillard, T ;
Rols, S ;
Anglaret, E ;
Laplaze, D ;
Sauvajol, JL .
CHEMICAL PHYSICS LETTERS, 2000, 316 (3-4) :186-190
[2]  
BARISCI JN, UNPUB
[3]   Carbon nanotube actuators [J].
Baughman, RH ;
Cui, CX ;
Zakhidov, AA ;
Iqbal, Z ;
Barisci, JN ;
Spinks, GM ;
Wallace, GG ;
Mazzoldi, A ;
De Rossi, D ;
Rinzler, AG ;
Jaschinski, O ;
Roth, S ;
Kertesz, M .
SCIENCE, 1999, 284 (5418) :1340-1344
[4]   Nanotube nanodevice [J].
Collins, PG ;
Zettl, A ;
Bando, H ;
Thess, A ;
Smalley, RE .
SCIENCE, 1997, 278 (5335) :100-103
[5]   NEW ONE-DIMENSIONAL CONDUCTORS - GRAPHITIC MICROTUBULES [J].
HAMADA, N ;
SAWADA, S ;
OSHIYAMA, A .
PHYSICAL REVIEW LETTERS, 1992, 68 (10) :1579-1581
[6]   SINGLE-SHELL CARBON NANOTUBES OF 1-NM DIAMETER [J].
IIJIMA, S ;
ICHIHASHI, T .
NATURE, 1993, 363 (6430) :603-605
[7]   Resonant Raman scattering and the zone-folded electronic structure in single-wall nanotubes [J].
Kasuya, A ;
Sugano, M ;
Maeda, T ;
Saito, Y ;
Tohji, K ;
Takahashi, H ;
Sasaki, Y ;
Fukushima, M ;
Nishina, Y ;
Horie, C .
PHYSICAL REVIEW B, 1998, 57 (09) :4999-5001
[8]   Raman modes of metallic carbon nanotubes [J].
Pimenta, MA ;
Marucci, A ;
Empedocles, SA ;
Bawendi, MG ;
Hanlon, EB ;
Rao, AM ;
Eklund, PC ;
Smalley, RE ;
Dresselhaus, G ;
Dresselhaus, MS .
PHYSICAL REVIEW B, 1998, 58 (24) :16016-16019
[9]   Diameter-selective Raman scattering from vibrational modes in carbon nanotubes [J].
Rao, AM ;
Richter, E ;
Bandow, S ;
Chase, B ;
Eklund, PC ;
Williams, KA ;
Fang, S ;
Subbaswamy, KR ;
Menon, M ;
Thess, A ;
Smalley, RE ;
Dresselhaus, G ;
Dresselhaus, MS .
SCIENCE, 1997, 275 (5297) :187-191
[10]   Large-scale purification of single-wall carbon nanotubes: process, product, and characterization [J].
Rinzler, AG ;
Liu, J ;
Dai, H ;
Nikolaev, P ;
Huffman, CB ;
Rodriguez-Macias, FJ ;
Boul, PJ ;
Lu, AH ;
Heymann, D ;
Colbert, DT ;
Lee, RS ;
Fischer, JE ;
Rao, AM ;
Eklund, PC ;
Smalley, RE .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1998, 67 (01) :29-37