Highly porous, homochiral metal-organic frameworks: Solvent-exchange-induced single-crystal to single-crystal transformations

被引：329

作者：

Wu, CD ^{[1
]}

Lin, WB ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 13期

关键词：

chirality; crystal engineering; functional materials; heterogeneous catalysis; metal-organic frameworks;

D O I：

10.1002/anie.200462711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Change and change about: Highly porous, homochiral metal-organic frameworks (MOFs) undergo reversible single-crystal to single-crystal and single-crystal to amorphous to single-crystal structural transformations when exposed to solvent vapors or air. These results suggest that true heterogeneous asymmetric catalysts can be built from homochiral MOFs. (Chemical Equation Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1958 / 1961

页数：4

共 35 条

[1]

[Anonymous], 2004, Angew. Chem, V116, P2388, DOI DOI 10.1016/j.jechem.2020.01.001

[2] Permanent microporosity and enantioselective sorption in a chiral open framework [J].